Also the theme song to Bond Movie Casino Royale

First the Opening Riff-

E|----------------------|-----------------------|
B|----------------------|---------------------7-|
G|---6---6b7----6---6b7-|---6---6b7----6--------|
D|-9---9------9---9-----|-9---9------9---9------|
A|----------------------|-----------------------|
E|----------------------|-----------------------|

Then The horns come in

Meanwhile, below the opening riff are a few power chords-

E|---------------|-REPEAT
B|---------------|-REPEAT
G|---------------|-REPEAT
D|-9-9-5-5-2-2---|-REPEAT
A|-9-9-5-5-2-2---|-REPEAT
E|-7-7-3-3-0-0---|-REPEAT

Then we get this nice little run that leads into the vocals-

E|-----------|
B|-----------|
G|-6b7-------|
D|-----9-7---|
A|---------9-|
E|-----------|

I Will have the chords/bass notes below the song part
and the occasional input from the lead guitar above it

E|----2----------------------3------------------------------2-|
B|---3----------------------3------------------------------3--|
G|--4----------------------3------------------------------4---|
D|-4----------------------5------------------------------4----|
A|------------------------------------------------------------|
E|------------------------------------------------------------|
VERSE                  Last section of tab below 2ndx only Look under Here
E|*|---|
B|*|---|
G|*|---|
D|*|---|
A|*|-4-|
E|*|-2-|

===========================================================================
PRELUDE TO CHORUS
E|*>-----------|
B|*>-----------|
G|*>-----------|
D|*>-----------|
A|*>hold5----4-|
E|*>hold3----2-|

===========================================================================
CHORUS
E|-----|-----|-----|---|-----|-----|---|---|-----|-----|---|---|---|---|---|---|---|------|
B|-----|-----|-----|---|-----|-----|---|---|-----|-----|---|---|---|---|---|---|---|------|
G|-----|-----|-----|---|-----|-----|---|---|-----|-----|---|---|---|---|---|---|---|------|
D|-----|-----|-----|---|-----|-----|---|---|-----|-----|---|---|---|---|---|---|---|------|
A|-9-9-|-5-5-|-2-2-|-2-|-9-9-|-5-5-|-2-|-2-|-9-9-|-5-5-|-2-|-2-|-5-|-5-|-2-|-2-|-2-|-2-|--|
E|-7-7-|-3-3-|-0-0-|-0-|-7-7-|-3-3-|-0-|-0-|-7-7-|-3-3-|-0-|-0-|-3-|-3-|-0-|-0-|-0-|-0-|--|


E|--------------|
B|--------------|
G|--------------|
D|-9-9-5-5-2-2--|
A|-9-9-5-5-2-2--|
E|-7-7-3-3-0-0--|

And thats just about it! for the rest of the song, keep playing the chorus chord 
I hope this tab helped you.